Section 3. Composition/information on ingredients

Section 11. Toxicological information

Section 13. Disposal considerations

Section 14. Transport information

Section 15. Regulatory information

Section 16. Other information

See toxicological information (Section 11)

Home > SAFETY DATA SHEETS > TURF RENU

Conforms to HazCom 2012/United States

SAFETY DATA SHEET

Section 1. Identification
GHS product identifier Other means of identification Product type Identified uses Not available. Supplier's details Emergency telephone number (with hours of operation)		: Turf Renu : Not available. : Liquid. : Renu Chem IncRenu Cleaners LLC 572 Malloy Ct Corona Ca 92880 Tel: 951 736 8072 Toll Free: 800 721 5572 Fax: 951 344 0466 Email: [email protected]Email: [email protected] Web site: www.renuchem.comWeb site: www.renucleaners.com : CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7)
Section 2. Hazards identification
OSHA/HCS status	: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification of the substance or mixture GHS label elements	: SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A AQUATIC HAZARD (ACUTE) - Category 3

Signal word	: Warning
Hazard statements Precautionary statements	: Causes serious eye irritation. Harmful to aquatic life.
Prevention	: Wear eye or face protection. Avoid release to the environment. Wash hands thoroughly after handling.
Response	: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention.
Storage	: Not applicable.
Disposal	: Dispose of contents and container in accordance with all local, regional, national and international regulations.

Hazard pictograms :

Hazards not otherwise : None known. classified

Substance/mixture	:	Mixture
Other means of identification	:	Not available.

CAS number/other identifiers

	Turf Renu
Section 2. Hazards identification

CAS number : Not applicable. Product code : Not available.

Ingredient name	%	CAS number
Sodium xylenesulphonate	5 - 10	1300-72-7
Citric Acid	5 - 10	77-92-9
Alcohols, C12-14, ethoxylated	0.1 - 1	68439-50-9
Sodium nitrate	0.1 - 1	7631-99-4
Poly(oxy-1,2-ethanediyl), α-(3-carboxy-1-oxo-3-sulfopropyl)-ω-(dodecyloxy)-, sodium salt (1:2)	0.1 - 1	39354-45-5

Any concentration shown as a range is to protect confidentiality or is due to batch variation.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures

Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.

Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If

not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Maintain an open airway. Get medical attention if symptoms occur.

Skin contact : Flush contaminated skin with plenty of water. Get medical attention if symptoms occur.

Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms occur.

Most important symptoms/effects, acute and delayed Potential acute health effects

Eye contact : Causes serious eye irritation.

Inhalation : No known significant effects or critical hazards. Skin contact : No known significant effects or critical hazards.

Ingestion : Irritating to mouth, throat and stomach.

Over-exposure signs/symptoms

Eye contact : Adverse symptoms may include the following:

pain or irritation watering redness

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	Turf Renu
Section 4. First aid measures

Inhalation: No known significant effects or critical hazards.
Skin contact : No known significant effects or critical hazards.
Ingestion: No known significant effects or critical hazards.
Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically.

Specific treatments: No specific treatment.

Protection of first-aiders: It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

Section 5. Fire-fighting measures
Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Hazardous thermal decomposition products Special protective actions for fire-fighters Special protective equipment for fire-fighters	: : : : : :	Use an extinguishing agent suitable for the surrounding fire. None known. This material is harmful to aquatic life. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Sulfur oxides metal oxide/oxides No special measures are required. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Section 6. Accidental release measures
Personal precautions, protect For non-emergency personnel For emergency responders Environmental precautions Methods and materials for co	iv : : : nt	e equipment and emergency procedures Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For nonemergency personnel". Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. ainment and cleaning up
Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com			*3/10*

	Turf Renu
Section 6. Accidental release measures

Spill : Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling

Protective measures

Advice on general occupational hygiene

Conditions for safe storage, including any incompatibilities

Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Avoid release to the environment. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.

Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. See also Section 8 for additional information on hygiene measures.

Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits None.

Appropriate engineering : Good general ventilation should be sufficient to control worker exposure to airborne controls contaminants.

Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure controls they comply with the requirements of environmental protection legislation.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location.

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.

Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.

Turf Renu
Section 8. Exposure controls/personal protection
Body protection Other skin protection Respiratory protection	: Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Section 9. Physical and chemical properties
Appearance Physical state Color Odor Odor threshold pH Melting point Boiling point Flash point Evaporation rate Flammability (solid, gas) Lower and upper explosive (flammable) limits Vapor pressure Vapor density Relative density Solubility Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Viscosity	: Liquid. [Opaque.] : Not available. : Fresh. : Not available. : 7 : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available. : Not available.
Section 10. Stability and reactivity

Reactivity		: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials		: The product is stable. : Under normal conditions of storage and use, hazardous reactions will not occur. : No specific data. : Reactive or incompatible with the following materials: oxidizing materials and alkalis.
			Turf Renu
	Section 10. Stability and reactivity

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should products not be produced.

Information on toxicological effects

Acute toxicity

Product/ingredient name	Result	Species	Dose	Exposure
Sodium xylenesulphonate	LD50 Oral	Rat	7200 mg/kg	-
Citric Acid	LD50 Oral	Rat	3 g/kg	-
Sodium nitrate	LD50 Oral	Rat	1267 mg/kg	-

Irritation/Corrosion

Product/ingredient name	Result	Species	Score	Exposure	Observation
Citric Acid	Eyes - Severe irritant	Rabbit	-	24 hours 750 µg	-
	Skin - Mild irritant	Rabbit	-	24 hours 500 mg	-
	Skin - Moderate irritant	Rabbit	-	0.5 mL	-
Poly(oxy-1,2-ethanediyl), α-(3carboxy-1-oxo-3-sulfopropyl)-ω-( dodecyloxy)-, sodium salt (1:2)	Skin - Mild irritant	Rabbit	-	500 mg	-

Sensitization

There is no data available.

Carcinogenicity

Classification

Product/ingredient name	OSHA	IARC	NTP	ACGIH	EPA	NIOSH
Sodium nitrate	-	2A	-	-	-	None.

Specific target organ toxicity (single exposure) There is no data available.

Specific target organ toxicity (repeated exposure) There is no data available.

Aspiration hazard

There is no data available.

Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion. routes of exposure

Potential acute health effects

Eye contact	:	Causes serious eye irritation.
Inhalation	:	No known significant effects or critical hazards.
Skin contact	:	No known significant effects or critical hazards.
Ingestion	:	Irritating to mouth, throat and stomach.

Symptoms related to the physical, chemical and toxicological characteristics

	Eye contact	: Adverse symptoms may include the following: pain or irritation watering redness
	Inhalation Skin contact	: No known significant effects or critical hazards. : No known significant effects or critical hazards.
			Turf Renu
Section 11. Toxicological information

Ingestion : No known significant effects or critical hazards.

Delayed and immediate effects and also chronic effects from short and long term exposure

Short term exposure

Potential immediate effects	:	No known significant effects or critical hazards.
Potential delayed effects	:	No known significant effects or critical hazards.
Long term exposure Potential immediate effects	:	No known significant effects or critical hazards.
Potential delayed effects	:	No known significant effects or critical hazards.

Potential chronic health effects

General	:	No known significant effects or critical hazards.
Carcinogenicity	:	No known significant effects or critical hazards.
Mutagenicity	:	No known significant effects or critical hazards.
Teratogenicity	:	No known significant effects or critical hazards.
Developmental effects	:	No known significant effects or critical hazards.
Fertility effects	:	No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

Route	ATE value
Oral	30000 mg/kg

Section 12. Ecological information

Toxicity

Product/ingredient name	Result	Species	Exposure
Citric Acid	Acute LC50 160000 µg/l Marine water	Crustaceans - Carcinus maenas - Adult	48 hours
Sodium nitrate	Acute EC50 522 mg/L Fresh water	Fish - Pimephales promelas	96 hours
	Acute LC50 161 mg/L Fresh water	Crustaceans - Hyalella azteca - Adult	48 hours
	Acute LC50 323 mg/L Fresh water	Daphnia - Daphnia magna - Neonate	48 hours
	Chronic NOEC 1.6 mg/L Fresh water	Fish - Coregonus clupeaformis - Embryo	120 days

Persistence and degradability There is no data available.

Bioaccumulative potential

Product/ingredient name	LogP_ow	BCF	Potential
Sodium xylenesulphonate	-3.12	-	low
Citric Acid	-1.8	-	low
Alcohols, C12-14, ethoxylated	-	237	low

Mobility in soil

Other adverse effects : No known significant effects or critical hazards.

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal

of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.

AERG : Not applicable.

Special precautions for user : Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.

Transport in bulk according : Not available. to Annex II of MARPOL 73/78 and the IBC Code

U.S. Federal regulations

Clean Air Act Section 112

(b) Hazardous Air

Pollutants (HAPs)

Clean Air Act Section 602 Class I Substances

Clean Air Act Section 602 Class II Substances

DEA List I Chemicals

(Precursor Chemicals)

DEA List II Chemicals

(Essential Chemicals)

TSCA 8(a) CDR Exempt/Partial exemption: Not determined

United States inventory (TSCA 8b): All components are listed or exempted.

Not listed

SARA 302/304

Composition/information on ingredients

No products were found.

SARA 304 RQ : Not applicable.

SARA 311/312

Classification : Fire hazard

Immediate (acute) health hazard

Composition/information on ingredients

Name	%	Fire hazard	Sudden release of pressure	Reactive	Immediate (acute) health hazard	Delayed (chronic) health hazard
Sodium xylenesulphonate	5 - 10	No.	No.	No.	Yes.	No.
Citric Acid	5 - 10	No.	No.	No.	Yes.	No.
Alcohols, C12-14, ethoxylated	0.1 - 1	No.	No.	No.	Yes.	No.
Sodium nitrate	0.1 - 1	Yes.	No.	No.	Yes.	No.
Poly(oxy-1,2-ethanediyl), α-(3-carboxy-1-oxo-3sulfopropyl)-ω-(dodecyloxy)-, sodium salt (1:2)	0.1 - 1	No.	No.	No.	Yes.	No.

SARA 313

	Product name	CAS number	%
Form R - Reporting requirements	Sodium nitrate	7631-99-4	0.1 - 1
Supplier notification	Sodium nitrate	7631-99-4	0.1 - 1

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. State regulations

Massachusetts

New York

New Jersey

Pennsylvania

California Prop. 65

No products were found.

The following components are listed: Sodium nitrate None of the components are listed.

None of the components are listed.

The following components are listed: Sodium nitrate

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Soil/water partition coefficient (K_OC)

There is no data available.

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Turf Renu

Section 12. Ecological information

History

Date of issue mm/dd/yyyy

Version

Revised Section(s)

Prepared by

Key to abbreviations

05/15/2014

Not applicable.

KMK Regulatory Services Inc.

ATE = Acute Toxicity Estimate

BCF = Bioconcentration Factor

GHS = Globally Harmonized System of Classification and Labelling of Chemicals

IATA = International Air Transport Association

IBC = Intermediate Bulk Container

IMDG = International Maritime Dangerous Goods

LogPow = logarithm of the octanol/water partition coefficient

MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations

Notice to reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.